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[3] [5] Topical application also keeps the copper load overwhelmingly local: intact stratum corneum is a substantial barrier to a ~403 Da charged metal complex, which limits systemic copper exposure the same barrier property that limits topical efficacy is what limits topical copper risk

10.1016/B978-0-12-803158-2.00025-4 Plant Metal and Interaction 45 KumarS.TrivediP