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If B were less soluble, it would be impossible to obtain pure A by this method in a single step, because some of the less soluble compound (B) will always be present in the solid that crystallizes from solution.
Shah Z, Kampfrath T, Deiuliis JA, Zhong J, Pineda C, Ying Z, Xu X, Lu B, Moffatt-Bruce S, Durairaj R, Sun Q, Mihai G, Maiseyeu A, Rajagopalan S (2011) Long-term dipeptidyl-peptidase 4 inhibition reduces atherosclerosis and inflammation via effects on monocyte recruitment and chemotaxis
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By the time he posted on the forum he had effectively been pushed out of the regulated system into the grey market by the prescribing protocol itself