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In older adults with mild cognitive impairment (MCI) GSH levels in both hippocampus and ventromedial frontal cortex were positively correlated with general cognitive integrity but negatively correlated with cognitive flexibility (Mandal et al., 2015)

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2.4 Sample preparation For LCQTOF-MS/MS analysis, 1 mg of powder or homogenized tablet was dissolved or extracted using 5 mL of a 1:1:1 (v/v/v) mixture of water/methanol/acetonitrile, assisted by ultrasonication for 10 min, and afterwards filtered by a Whatman 0.2 m pore size polytetrafluoroethylene (PTFE) filter medium (GE Healthcare, Chicago, IL, United States)

more specifically, your CYP1A2 gene that determines how quickly you metabolize caffeine