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Indeed, the reversible one-electron reduction of Cu(II) does occur, as exemplified by the thiosemicarbazone complex of Cu(II) in the elesclomol [330, 331] (Table 3)

This is a kind of end-product inhibition that prevents the GSH concentration from rising too high

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Intriguingly, it's involved in keeping oxidative stress at bay, ensuring that those nasty free radicals don't tarnish your skin's beautiful appearance

Trace amounts can form during production but the EU's Scientific Committee on Consumer Safety has concluded that levels at/below 10 ppm in finished products are safe (commercial products consistently fall within acceptable margins)