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This selectivity mainly relies on the "pore size screening" effect of tight junctions: small molecules can be absorbed through the tightly connected "paracellular pathway" or the "transcellular pathway" of epithelial cells

In addition to PARP10, TRPT1, a PARP homolog, also catalyzes the ADP-ribosylation of RNA

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Giustarini D, Colombo G, Garavaglia ML, Astori E, Portinaro NM, Reggiani F, Badalamenti S, Aloisi AM, Santucci A, Rossi R, Milzani A, Dalle-Donne I (2017) Assessment of glutathione/glutathione disulphide ratio and S-glutathionylated proteins in human blood, solid tissues, and cultured cells

doi: 10.2337/dc14-1958 209 GallwitzBVaagAFalahatiAMadsbadS