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In 2017, another clinical study showed that melatonin intake (10 mg/day, P.O for 12 weeks) increased serum GSH levels while reducing serum MDA and protein carbonyl (PCO) in CHD patients with type 2 diabetes

J.WangC.et al (2016)

GHK-Cu and Extracellular Matrix Research Research confirms that GHK stimulates synthesis of collagen, dermatan sulfate, chondroitin sulfate, and the small proteoglycan decorin, while also modulating metalloproteinase activity and their inhibitors making it a key compound in extracellular matrix research

First small molecule permeable and selective for this target

In fact, insulin was the first peptide ever made in a lab by scientists (called a synthetic peptide), and it's been used to treat people with type 1 diabetes since 1923